Post Index 2

by James

Here’s an index of posts for relevant topics in Organic Chemistry 1 (first-semester organic chemistry).

From Gen Chem to Organic Chem Alkanes and Nomenclature
Functional Groups Khan Academy for Organic Chemistry
Everything I Know About Stereochemistry I Learned from Cats More On Stereochemistry
Key Reactions of Org 1 Resonance (and dipoles)
Understanding Mechanisms (How Electrons Flow) Acid Base Reactions
Substitution Reactions Rearrangement Reactions
Walkthrough of Elimination Reactions SN1/SN2/E1/E2 Decision

 

From Gen Chem to Organic Chem
General Chem and Organic Chem: How are they Different? Part 1: The Atom
Part 2: Electrons and Orbitals Part 3: Effective Nuclear Charge
Part 4: Chemical Bonding Part 5: Understanding Periodic Trends
Part 6: Lewis Structures, A Fable Part 7: Lewis Structures
Part 8: Ionic and Covalent Bonding Part 9: Acids and Bases
Part 10: Hess’ Law Part 11: The Second Law of Thermodynamics
Part 12: Chemical Kinetics Part 13: Equilibria
Part 14: Wrapup

 

Alkanes and Nomenclature
The Many, Many Ways of Drawing Butane Hidden Hydrogens, Hidden Lone Pairs, Hidden Counterions
The Principle of Least Effort Don’t Be Futyl, Learn The Butyls
Condensed Formulas: Deciphering The Brackets The Ups And Downs of Cyclohexanes
Functional Group Priorities for Nomenclature 8 Types Of Arrows In Organic Chemistry, Explained
Common Mistakes – Pentavalent Carbon Primary, Secondary, Tertiary, Quaternary 
9 Weird Nomenclature Conventions To Know

 

Functional Groups
Partial Charges 3 Trends That Affect Boiling Points
Sigma Bonds Come in Six Varieties – Pi Bonds Come In One Meet The Most Important Functional Groups
4 Intermolecular Forces And How They Affect Boiling Points How To Calculate Formal Charge
How Symmetry Is Related To Melting Points and Boiling Points

 

Khan Academy for Organic Chemistry
Part 1 – Videos 1-12 (mostly alkane nomenclature)  Part 2 – Videos 13-26 (mostly conformations)
Part 3 – Videos 27-37 (mostly substitution reactions)  Part 4 – Videos 38-51 (mostly substitution and elimination)
Part 5 – Videos 52-64 (mostly aldehydes/ketones)  Part 6 – Videos 65-73 (carboxylic acids)
 In Summary: How Useful Are Khan Academy Videos?

 

Everything I Know About Stereochemistry I Learned From Cats
Screw Organic Chemistry, I’m Just Going to Write About Cats On Cats: Conformations and Configurations
On Cats: Cat Line Diagrams On Cats: Newman Projections
On Cats: Enantiocats On Cats: Enantiocats vs. Diastereocats 
On Cats: Stereocenters On Cats: The Fischer Projection
On Cats: Moe The Meso Cat Fare Thee Well Oh Cats of Jerusalem

 

More On Stereochemistry
The Single Swap Rule The Meso Trap
How To Do Bond Rotations What’s A Racemic Mixture?
Homotopic, Enantiotopic, Diastereotopic Selective Versus Specific
Ephedrine and Pseudoephedrine

 

Key Reactions of Org 1
The Most Important Question To Ask When Learning A New Reaction  4 Major Classes of Reactions In Org 1
Introduction to Acid Base Reactions Introduction to Substitution Reactions
Introduction to Addition Reactions Introduction to Elimination Reactions
Introduction to Rearrangement Reactions Introduction to Free Radical Reactions
Introduction to Oxidative Cleavage Reactions Draw The Ugly Version First

 

Understanding Where Electrons Are – Dipoles And Resonance
The Second Most Important Question To Ask When Learning A New Reaction  Watch Out! Formal Charge Can Lie
Introduction to Resonance Introduction to Resonance (2) – Curved Arrows!  
Evaluating Resonance Forms (1) – The Rule of Least Charges Evaluating Resonance Forms (2) – Applying Electronegativity
Evaluating Resonance Forms (3) – Negative Charges Evaluating Resonance Forms (4) – Positive Charges 
Exploring Resonance (1) – Pi Donation Applying Resonance (2) – Pi Acceptors
In Summary – Resonance Common Mistakes – How Not To Draw Resonance Curved Arrows
How To Apply Electronegativity and Resonance To Understand Reactivity 3 Factors That Stabilize Carbocations
3 Factors that Destabilize Carbocations

 

Understanding How Reactions Work – Electron Flow
How (and why) Electrons Flow  The Third Most Important Question To Ask When Learning A New Reaction
Common Mistakes – Formal Charge Can Mislead  Seven Factors That Stabilize Negative Charge (and why it matters)
Curved Arrows – Initial Tails and Final Heads Seven Factors That Stabilize Positive Charge 
Grossman’s Rule Hammond’s Postulate
Three Classes of Nucleophiles What’s A Transition State? 
“Nucleophile Attacks Electrophile”

 

Acid-Base Reactions
Introduction to Acid Base Reactions Walkthrough of Acid-Base Reactions (1)
Walkthrough of Acid-Base Reactions (2) – Basicity Acid-Base Reactions (3) – Acidity Trends
Acid Base Reactions (4) – pKa Acid-Base Reactions (5) – How To Use a pKa Table
A Handy Rule of Thumb for Acid-Base Reactions Acid-Base Reactions Are Fast
Acid-Base Reactions – What’s the Point? 5 Key Factors That Influence Acidity
The pKa Table Is Your Friend

 

Substitution Reactions
Introduction to Substitution Reactions Walkthrough of Substitution Reactions (1) 
Nucleophiles And Electrophiles  Nucleophilicity Versus Basicity
What Makes A Good Nucleophile? What Makes A Good Leaving Group?
Leaving Groups Are Nucleophiles Acting In Reverse Two Types of Substitution Reactions
The SN2 Mechanism Why The SN2 Is Powerful
The SN1 Mechanism The Conjugate Acid Is A Better Leaving Group
Comparing the SN1 and E1 Reactions All About Solvents
Steric Hindrance is Like A Fat Goalie Common Blind Spot: Intramolecular Reactions
The Conjugate Base Is Always A Stronger Nucleophile

 

Rearrangement Reactions
Introduction to Rearrangement Reactions Rearrangement Reactions – Hydride Shifts
Rearrangement Reactions – Alkyl Shifts 3 Factors That Stabilize Carbocations

 

Walkthrough of Elimination Reactions
Introduction to Elimination Reactions Walkthrough of Elimination Reactions (1) – Introduction
Zaitsev’s Rule Elimination Reactions Are Favored By Heat
Two Types of Elimination Reactions The E1 Mechanism
The E2 Mechanism Comparing the E1 and E2 Reactions
Elimination Reactions And Cyclohexane Rings Bulky Bases In Elimination Reactions
Comparing The SN1 and E1 Reactions E1 Reactions With Rearrangements 

 

Walkthrough of SN1/SN2/E1/E2 Decision
Trapped In SN1/SN2/E1/E2 Hell? Some Resources

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