Addition of Dichlorocarbene to alkenes to give dichlorocyclopropanes

Description: Alkenes treated with chloroform (CHCl3) and strong base will form dichlorocarbenes, which add to alkenes to form cyclopropanes.
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- 1,4-addition of enolates to enones (“The Michael Reaction”)
- 1,4-addition of nucleophiles to enones
- 1,4-addition of organocuprates (Gilman reagents) to enones
- Acidic cleavage of ethers (SN2)
- Addition of aqueous acid to alkenes to give alcohols
- Addition of Dichlorocarbene to alkenes to give dichlorocyclopropanes
- Addition of dichloromethylene carbene to alkenes
- Addition of Grignard reagents to aldehydes to give secondary alcohols
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- Addition of Grignard reagents to formaldehyde to give primary alcohols
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- Addition of HBr once to alkynes to give alkenyl bromides
- Addition of HBr to Alkenes
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- Addition of HCl to Alkenes to Give Alkyl Chlorides
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- Formation of Acetals from Aldehydes and Ketones
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- Formation of bromohydrins from alkenes using water and NBS
- Formation of Carboxylic Acids from Acyl Chlorides
- Formation of carboxylic acids from Grignard reagents and CO2
- Formation of chlorohydrins from alkenes using water and Cl2
- Formation of Cyanohydrins from ketones and aldehydes
- Formation of cyclopropanes from alkenes using methylene carbene (:CH2)
- Formation of Diazonium Salts from Aromatic Amines
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- Formation of epoxides from alkenes using m-CPBA
- Formation of epoxides from bromohydrins
- Formation of Gilman reagents (organocuprates) from alkyl halides
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- Formation of Grignard Reagents from Alkyl Halides
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- Oxidative cleavage of alkenes to ketones/carboxylic acids using KMnO4
- Oxidative Cleavage of Alkynes with KMnO4
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- Oxymercuration of Alkenes to form Ethers using Hg(OAc)2
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- Substitution (SN1) with hydride shift
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- Transesterification promoted by alkoxides
- Wittig Reaction – conversion of ketones/aldehydes to alkenes
- Wolff Kishner Reaction – conversion of ketones/aldehydes to alkanes
- Wolff Rearrangement
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