Making Alkyl Halides From Alcohols
Making Alkyl Halides From Alcohols In today’s post we show that treating alcohols with HCl, HBr, or HI (which all fall under the catch-all term
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Rearrangements in Alkene Addition Reactions
Carbocation Rearrangements In Alkene Addition Reactions Alkene addition reactions that go through carbocation intermediates (such as addition of HCl, HBr, HI and H3O+) may occur
Read moreElimination (E1) Reactions With Rearrangements
Elimination Reactions (E1) That Occur With Rearrangements – Hydride Or Alkyl Shifts Where there are carbocations (see last post), rearrangement reactions are never far behind.
Read moreCarbocation Rearrangement Reactions (2): Alkyl Shifts
Alkyl Shifts In Carbocation Rearrangement Reactions, Including Ring Expansion Hydride shifts can sometimes occur when a more stable carbocation can be formed through migration of
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The Pinacol Rearrangement The pinacol rearrangement is an acid-catalyzed rearrangement of 1,2-diols (vicinal diols) The acid serves to protonate one of the hydroxyl groups, which
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