Hell-Vollhard-Zelinsky Reaction

by James

Description: The Hell-Vollhard-Zelinsky [HVZ] reaction is a means of converting a carboxylic acid to a brominated carboxylic acid (the bromine ends up on the alpha carbon of the carboxylic acid).
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{ 4 comments… read them below or add one }

Petr October 18, 2012 at 7:22 am

hell-volhard-zElinsky

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james October 18, 2012 at 5:19 pm

Oops. Thanks

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Doug April 22, 2014 at 5:40 pm

what would happen to the brominated carboxylic acid product if you next added H3O+ ?

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James April 25, 2014 at 11:04 pm

Probably not that much. Over time, you might start getting replacement of the Br with OH, but that would require water acting as a nucleophile. With enough heat you might start to eliminate to give the double bond. However both of these are going to be fairly slow reactions.

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