Reactions on the “Benzylic” Carbon: Bromination And Oxidation
The carbon adjacent to an aromatic ring – the “benzylic” carbon – can participate in several useful and interesting reactions. Today we’ll provide examples and
Read morebr2
Alkene Addition Pattern #2: The “Three-Membered Ring” Pathway
The “Three-Membered Ring” Pathway In Alkene Mechanisms: Halogenation, Oxymercuration, Halohydrin Formation, and Acidic Epoxide Opening In the last post we walked through a proposal for
Read moreBromonium Ion Formation: A (Minor) Arrow-Pushing Dilemma
Bromonium Ion Formation: For Some Concerted Reactions Drawing Reasonable Curved Arrow Mechanisms Can Be Tricky Up to now, drawing out reaction mechanisms using the curved
Read moreAnother awesome example of acid catalysis: Acids catalyze keto-enol tautomerism
Between posts on tautomerism and on lewis acid catalysis, I neglected to mention a really important point in carbonyl chemistry that illustrates another facet of
Read more