Master Organic Chemistry Reaction Guide

Formation of carboxylic acids from Grignard reagents and CO2

Description: Grignard reagents will add to carbon dioxide, forming carboxylate salts. After acidic workup, carboxylic acids are formed.

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Real-World Examples:

Org. Synth. 1925, 5, 75

DOI Link:10.15227/orgsyn.005.0075

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Org. Synth. 1928, 8, 104

DOI Link: 10.15227/orgsyn.008.0104

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Org. Synth. 1931, 11, 80

DOI Link: 10.15227/orgsyn.011.0080

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Org. Synth. 1941, 21, 77

DOI Link: 10.15227/orgsyn.021.0077

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Org. Synth. 1959, 39, 19

DOI Link: 10.15227/orgsyn.039.0019

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Org. Synth. 1979, 59, 85

DOI Link: 10.15227/orgsyn.059.0085

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