Keto-Enol Tautomerism
An extensive introduction to keto-enol tautomerism in aldehydes and ketones, with mechanisms, quizzes, key concepts, references and more.
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Pyranoses and Furanoses: Ring-Chain Tautomerism In Sugars
Pyranoses , Furanoses, Straight-Chain Glucose, And Ring-Chain Tautomerism Sugars such as glucose exist in equilibrium between their open-chain form and various cyclic forms where an
Read moreAlkyne Hydroboration With “R2BH”
Hydroboration-Oxidation of Alkynes As seen in the previous chapter, hydroboration of alkenes with borane (BH3) followed by oxidation (NaOH, H2O2) gives alcohols with anti-Markovnikov regioselectivity
Read moreHydration and Oxymercuration of Alkynes
Hydration and Oxymercuration of Alkynes Via Keto-Enol Tautomerism Alkyne chemistry bears many resemblances to alkene chemistry, but in these first few posts on the subject,
Read moreThe Hell–Volhard–Zelinsky Reaction
A Guided Tour Through “Hell” : The Hell Volhard Zelinsky (HVZ) Reaction The Hell-Volhard-Zelinsky reaction of carboxylic acids results in an alpha bromo carboxylic acid.The
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