Bond Strengths And Radical Stability
Bond Dissociation Energies And Radical Stability The last article discussed factors which stabilize – and destabilize – free radials. So how do we quantify free-radical
Read moreFree Radical Initiation: Why Is “Light” Or “Heat” Required?
Free-Radical Reactions Require Heat Or Light For Initiation (Bond-Breaking) If you come across just a few free-radical reactions, you should notice a familiar pattern. Every
Read moreInitiation, Propagation, Termination
Initiation, Propagation, and Termination In Free Radical Reactions In the previous post on free radical substitution reactions we talked about why heat or light is
Read moreMonochlorination Products Of Propane, Pentane, And Other Alkanes
How Many Monochlorination Isomers Are Formed From Free-Radical Chlorination Of Alkanes? Last time we covered a comparatively simple reaction: free-radical chlorination of methane to (CH4)
Read moreSelectivity In Free Radical Reactions
Free Radical Chlorination: Selectivity This post is all about the selectivity of free-radical halogenation: what does “selectivity” mean, anyway? And how do we calculate it? It’s often
Read moreThe Best Way To Spend Your First Two Weeks In Organic Chem
Advice on some topics on the internet can be so laughably bad. One example that immediately comes to mind is finding a job. How
Read moreSelectivity in Free Radical Reactions: Bromination vs. Chlorination
The Selectivity of Free-Radical Bromination vs Chlorination. A Detailed Answer In last article on radicals (See Article – Selectivity in Free Radical Reactions) we saw
Read moreOrganic Chemistry For the MCAT
Many students taking organic chemistry one day plan to write the Medical College Admission Test (MCAT). A common question students have for me is what
Read moreSuccess Stories: How Stu Aced Organic Chemistry
I recently got an email from a reader, Stu (not his real name) who told me he got an A in Organic Chemistry 1, and
Read moreHalogenation At Tiffanys
Thinking Through The Selectivity of Bromination vs Chlorination: An Intuitive Analogy As we discussed in the last post on radicals, bromine radicals are considerably more
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