Today we’ll cover how to tell endo– and exo- products apart in the Diels-Alder reaction. Shortcut below. For the long-winded walkthrough with lots of examples, read more below. Table
Read moreAromatic vs Antiaromatic vs Non Aromatic Practice Exercises Our last post in this series on aromaticity went through the 4 conditions a molecule must fulfill
Read moreThe HOMO and LUMO In The Diels Alder Reaction The Diels-Alder reaction is a concerted reaction between a diene (with 4 pi-electrons) and a dienophile
Read moreAntiaromatic Compounds Are Unusually Unstable What are the key factors that determine whether a molecule is antiaromatic? It is similar to the requirements for aromaticity,
Read more[Advanced] Secondary Orbital Interactions – A Rationale For Why Endo Products Are Favored In The Diels-Alder Reaction In our last post, we noted that endo products tend to be
Read moreAre These Molecules Enantiomers, Diastereomers or The Same? A classic exam question is to determine whether two molecules are enantiomers, diastereomers or the same. This
Read moreThe Pi Molecular Orbitals of Benzene Today, let’s go through how to draw out the molecular orbitals of benzene. We’ll compare them with the molecular
Read moreKinetic and Thermodynamic Control In The Diels-Alder Reaction: The Diels Alder Reaction Is Reversible At High Temperatures We’ve seen that the products of addition to
Read moreMechanism and Examples of the Retro Diels-Alder Reaction In the last post in this series on the Diels-Alder [See: Diels-Alder Reaction: Kinetic and Thermodynamic Control]
Read moreDetermining R and S Configurations of Newman Projections How do you determine R and S configurations on Newman projections? The key is to be able to quickly
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