Deciding SN1/SN2/E1/E2 (2) – The Nucleophile/Base
SN1 / SN2 / E1 / E2 The Nucleophile / Base This article assumes you understand the mechanisms of the SN1/SN2/E1 and E2 reactions. For
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The Most Interesting Man In The World passed away the other week. No, not THAT guy. He’s just an actor. The OTHER guy. The OTHER
Read moreFree Radical Reactions
Free Radical Reactions – Chlorination of Methane Alkanes are pretty boring, chemically speaking. They don’t tend to undergo many reactions. However, when they are treated
Read more3 Factors That Stabilize Free Radicals
What Factors Affect Free-Radical Stability? In the last article we introduced free radicals – neutral, electron-deficient chemical species with a partially filled orbital – and
Read moreBond Strengths And Radical Stability
Bond Dissociation Energies And Radical Stability The last article discussed factors which stabilize – and destabilize – free radials. So how do we quantify free-radical
Read moreFree Radical Initiation: Why Is “Light” Or “Heat” Required?
Free-Radical Reactions Require Heat Or Light For Initiation (Bond-Breaking) If you come across just a few free-radical reactions, you should notice a familiar pattern. Every
Read moreInitiation, Propagation, Termination
Initiation, Propagation, and Termination In Free Radical Reactions In the previous post on free radical substitution reactions we talked about why heat or light is
Read moreMonochlorination Products Of Propane, Pentane, And Other Alkanes
How Many Monochlorination Isomers Are Formed From Free-Radical Chlorination Of Alkanes? Last time we covered a comparatively simple reaction: free-radical chlorination of methane to (CH4)
Read moreSelectivity In Free Radical Reactions
Free Radical Chlorination: Selectivity This post is all about the selectivity of free-radical halogenation: what does “selectivity” mean, anyway? And how do we calculate it? It’s often
Read moreThe Best Way To Spend Your First Two Weeks In Organic Chem
Advice on some topics on the internet can be so laughably bad. One example that immediately comes to mind is finding a job. How
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