How To Properly Draw Your First Cyclohexane Chair, Using The “Parallelogram Technique”
Now that we’ve had an aerial tour of the cyclohexane chair, we’re going to move on to a very important skill: how to properly draw one of these beasties.
There are several techniques for properly draw a cyclohexane chair.
In this video, I walk through what I consider to be the most completely idiot-proof way to draw a chair, by first drawing a parallelogram (something you should already know how to do). Using this as the “base” of our chair, we then draw flaps moving up and down (representing the head and footrest), then put in the axial and equatorial groups.
Importantly, we can use this method to draw a chair in either the “left hand” or the “right hand” version of a cyclohexane chair, which becomes important, once we learn about chair flips (that’s next!)
In time and with a little bit of practice, you won’t need to draw the parallelogram to guide you. Think of it as a set of training wheels that you will later discard once you don’t need them anymore.
How NOT To Draw A Cyclohexane Chair
Having an easy-to-remember technique is crucial.
Otherwise, your first few attempts in drawing a cyclohexane chair from memory might see you end up with one of these “variations” from a rogue’s gallery of 4 ways to screw up drawing a cyclohexane chair (and don’t feel bad – we’ve all done it . The trick is to make all the necessary mistakes before you take your midterm).
Bad Chair #1: Crow’s Foot
Bad Chair #2: Crow’s Foot (slight return)
Bad Chair #3: “The Lightning Bolt” [h/t Chemjobber]
|What’s wrong? The axial and equatorial positions are drawn in properly, but the chair is drawn so thinly that the front carbons obscure the groups on the back carbons.How to fix: The angles at the “headrest” and “footrest” are too acute; open them up a bit. Also, stagger the two front carbons and the two back carbons so that they’re not directly in front of each other.|
Bad Chair #4: “Mr. Fatty”